Founding Research Journal

Founding Research Journal

Effect of Immersion Time and Temperature on the Interface Characteristics ‎of Pure Aluminium and Plain Carbon Steel

Document Type : Original Research Article

Authors
1 M.Sc. Student, School of Metallurgy and Materials Engineering, Iran University of Science and Technology, Tehran, Iran‎
2 Associate Professor, ‎School of Metallurgy and Materials Engineering, Iran University of Science and Technology, Tehran, Iran.‎
10.22034/frj.2018.108915.1014
Abstract
To reach an acceptable bimetallic composite product from two metals, interface characteristics needs to be investigated. In this work joining of commercial aluminium and a plain carbon steel and the formation and growth of intermetallic compounds at the interface was investigated. Steel rods were immersed into the pure aluminium melt at temperatures of 680, 720, 760 and 800 Celsius and kept for different times of 5, 10, 15 and 20 minutes, respectively and then were taken out and cooled in the air. After cross sectioning and sampling, the microstructure of interface between steel substrate and aluminium was studied by optical microscopy (OM), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and Vickers hardness tests. The results showed that two intermetallic compounds, FeAl3 and Fe2Al5 are formed in the interface. Increasing the holding time and temperature changed the interface thickness and had no clear effects on the intermetallics types. Vickers hardness tests showed that the hardness of reaction interface was higher than aluminum and steel substrate due to presence of the above mentioned intermetallics. Kinetic of intermetallics formation are discussed.
Keywords

[1] ASM Metals Handbook Vol.5, Surface Engineering, ASM International, 1992.
[2]  Aguado E., Baquedano A., Uribe U., Fernandez-Calvo A. L., Niklas A., Comparative study of different interfaces of steel inserts in aluminium castings, Materials Science Forum, 2013, 765, 711-715.
[3]  Rana-Rajesh-Purohit R.S., Das S., Review of recent studies in Al matrix composites, International Journal of Scientific and Engineering Research, 2012, 3(6) 2229-5518.
[4]  Manikanadan G., Uthayakumar M., Aravindan S., Machining and simulation studies of bimetallic pistons, International Journal of Advanced Manufacturing Technology, 2013, 66, 711-720.
[5]  Akbarifar M., Divandari M., Interface characterization of Al/Cast iron composite, Journal of Science and Technology of Composites, 2016, 3(3) 261-268 (In Persian).
[6]  Hiteh E., Divandari M., Gholami, M., Interface characterization of aluminum-copper bimetal composite produced via centrifugal casting, Journal of Science and Technology of Composites, 2017, 3(4) 343-350 (In Persian)
[7]  Hwang S.H., Song J.-H., Kim Y.S., Effects of carbon content of carbon steel on its dissolution into a molten aluminum alloy, Materials Science and Engineering A, 2005, 390, 437–443.
[8]  Akdeniz M.V., Mekhrabov A.O., The effect of substitutional impurities on the evolution of Fe-Al diffusion layer, Acta Material. 1998, 46, 1185-1192.
[9]  Akdeniz M V, Mekhrabov A 0, Yilmaz T, The role of Si addition on the interfacial interaction in Fe-Al diffusion layer, Scripta MetaUurgica et Materialia, 1994, 3, 1723-1728.
[10] Tanaka Y., Kajihara M., Kinetics of isothermal reactive diffusion between solid Fe and liquid Al, Journal of Material Science, 2010, 45, 5676–5684.
[11] Cheng W.J., Wang Ch.J., Growth of intermetallic layer in the aluminide mild steel during hot-dipping, Surface & Coatings Technology, 2009, 204, 824–828.
[12] Bouche K., Barbier F., Coulet A., Intermetallic compound layer growth between solid iron and molten aluminium, Materials Science and Engineering A, 1998, 249, 167–175.
[13] Deqing W, Ziyuan S, Longjiang Z, A liquid aluminum corrosion resistance surface on steel substrate, Applied Surface Science, 2003, 214, 304-311.
[14] Kobayashi S., Yakou T., Control of intermetallic compound layers at interface between steel and aluminum by diffusion-treatment, Material Science and Engineering, 2002, 338, 44–53.
[15] Yajiang L., Juan W., Yonglan Z., Holly X., Fine structures in Fe3Al alloy layer of a new hot dip aluminized steel, Bulletin of Materials Science, 2002, 25(7) 635–639.
[16] Abro M. A., Lee D.B., Effect of Al hot-dipping on high-temperature corrosion of carbon steel in N2/0.1% H2S gas, Metals, 2016, 6(2) 38.
[17] Joshi V., Srivastava A., Shivpuri R., Intermetallic formation and its relation to interface mass loss and tribology in die casting dies, Wear, 2004, 256, 1232–1235.
[18] Tanaka Y, Kajihara M, Morphology of compounds formed by isothermal reactive diffusion between solid Fe and liquid Al, Materials Transactions, 2009, 50, 2212-2220.
[19] Shahverdi H.R., Ghomashchi M.R., Shabestari S., Hejazi J., Microstructural analysis of interfacial reaction between molten aluminium and solid iron, Journal of Materials Processing Technology, 2002, 124, 345-352.
[20] Bouayad A., Gerometta Ch., Belkebir A., Ambari A., Kinetic interactions between solid iron and molten aluminium, Materials Science and Engineering A, 2003, 363, 53–61.
[21] Dybkov V. I., Phase formation and diffusion in binary systems: Real facts and misleading views, Materials Science and Technology Conference and Exhibition, 2007, 3, 1797-1808.
[22] Dybkov V.I., The growth kinetics of intermetallic layers at the interface of a solid metal and a liquid solder, JOM, 2009, 61, 76-79.
[23] Tang N, Li Y P, Kurosu S, Koizumi Y, Matsumoto H, Chiba A, Interfacial reactions of solid Co and solid Fe with liquid Al, Corrosion Science, 2012, 60, 32–37.
[24] Liru F., Lin L., Analysis of coating microstructure of hot-dip aluminum of deformed low-carbon steel containing rare earth, Journal of Rare Earths, 2005, 23, 460-463.
[25] Nazari K.A., Shabestari S., Effect of micro alloying elements on the interfacial reactions between molten aluminum alloy and tool steel, Journal of Alloys and Compounds, 2009, 478, 523–530.
[26] Nishimoto S, Kobayashi S, Takada N, Matsuo T, Takeyama M, “Collected Abstracts of 2008 Autumn Meeting of the Japan Inst. Metals” , 2008,  82-87.
[27] Maitra T, Gupta S.P., Intermetallic compound formation in Fe–Al–Si ternary system: part II, Materials Characteristics, 2013, 49, 293–311.
[28] Takata N., Nishimoto M., Kobayashi S., Takeyama M., Crystallography of Fe2Al5 phase at the interface between solid Fe and liquid Al, Intermetallics, 2015, 67, 1-11.
[29] Deqing W., Phase evolution of an aluminized steel by oxidation treatment, Applied Surface Science, 2008, 254, 3026–3032.
[30] Springer H., Kostka A., Payton E.J., Raabe D., Kaysser-Pyzalla A., Eggeler G., On the formation and growth of intermetallic phases during interdiffusion between low-carbon steel and aluminum alloys, Acta Materialia, 2011, 59,  1586–1600.
[31] Sasaki T., Yakou T., Mochiduki K., Ichinose K., Effect of carbon contents in steel on alloy layer growth during hot-dip aluminum coating, ISIJ International, 2005, 45, 1887-1892.

  • Receive Date 30 November 2017
  • Revise Date 12 January 2018
  • Accept Date 21 January 2018